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Physical and Chemical Properties of Hydrogen Peroxide

Hydrogen Peroxide (H2O2) solutions are clear, colorless, water-like in appearance, and can be mixed with water in any proportion. At high concentrations, it has a slightly pungent or acidic odor.

H2O2 has a molecular weight of 34.02 and is nonflammable at any concentration. Its Chemical Abstracts Service Registry Number is 7722-84-1. Other physical and chemical properties of the two standard industrial strengths follow.


H2O2 Concentration35%50%
Active oxygen content, wt.%16.523.5
Density @ 68°F:
Specific gravity
lbs per gallon
gms-100% per mL

1.132
9.45
0.397

1.196
9.98
0.598
Apparent pH 2-31-2
Acidity, mg/L (as H2SO4) < 50< 50
Total heavy metals, mg/L < 1< 1
Freezing point, °F -27-62
Boiling point, °F 226237
Vapor pressure @ 86°F, mm Hg 2318
Viscosity:
@ 32°F, cp
@ 68°F, cp

1.81
1.11

1.87
1.17
Heat of decomposition, cal/gm 233335
Mole fraction 0.220.346






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